You can check your Macintosh System Profile. When you select the installed eSATA card, the Device ID will show either "0x6081" or "0x5081". The 3 Gigabit/second eSATA cards use the Marvell chip 88SX6081. The 1.5 Gigabit/second eSATA cards use the Marvell chip 88SX5081.
Macintosh bootable volumes are supported on the internal 2-port PCI card (part number TSATA) but are not supported on any of the other SATA cards at this time.
Under Mac OS X 10.3 and 10.4, a volume greater than 2TB will show as a 2TB volume due to a limitation in Apple's ATA layer (just above the driver). Sonnet plans to provide a 10.4 fix in the next driver release. Under Mac OS X 10.5 and 10.6, the full capacity of the RAID volume is available.