You can check your Macintosh System Profile. When you select the installed eSATA card, the Device ID will show either "0x6081" or "0x5081". The 3 Gigabit/second eSATA cards use the Marvell chip 88SX6081. The 1.5 Gigabit/second eSATA cards use the Marvell chip 88SX5081.
Macintosh bootable volumes are supported on the internal 2-port PCI card (part number TSATA) but are not supported on any of the other SATA cards at this time.